Karst weathering processes and landscapes

4487
Robert Johnston

The karst, Karst or karst relief, is a form of topography whose origin is due to weathering processes due to dissolution of soluble rocks such as limestone, dolomite and gypsum. These reliefs are characterized by presenting an underground drainage system with caves and drains.

The word karst comes from the German Karst, A word used to refer to the Italian-Slovenian area Carso, where karst landforms abound. The Royal Spanish Academy approved the use of both words "karst" and "karst", with equivalent meaning.

Figure 1. Anaga Mountains, Tenerife, Canary Islands, Spain. Source: Jan Kraus via flickr.com/photos/johny

Limestone rocks are sedimentary rocks mainly composed of:

  • Calcite (calcium carbonate, CaCO3).
  • Magnesite (magnesium carbonate, MgCO3).
  • Minerals in small quantities that modify the color and the degree of compaction of the rock, such as clays (aggregates of hydrated aluminum silicates), hematite (ferric oxide mineral FetwoOR3), quartz (silicon oxide mineral SiOtwo) and siderite (iron carbonate mineral FeCO3).

Dolomite is a sedimentary rock made up of the mineral dolomite, which is double carbonate of calcium and magnesium CaMg (CO3)two.

Gypsum is a rock composed of hydrated calcium sulfate (CaSO4.2HtwoO), which may contain small amounts of carbonates, clay, oxides, chlorides, silica and anhydrite (CaSO4).

Article index

  • 1 Karst weathering processes
  • 2 Geomorphology of karst reliefs
    • 2.1 -Internal karst or endocarstic relief
    • 2.2 -External karst, exocarstic or epigenic relief
  • 3 Karst formations as life zones
    • 3.1 Photic zones in karst formations
    • 3.2 Fauna and adaptations in the photic zone
    • 3.3 Other limiting conditions in karst formations
    • 3.4 Microorganisms of endocarstic areas
    • 3.5 Microorganisms of exocarstic zones
  • 4 Landscapes of karst formations in Spain
  • 5 Landscapes of karst formations in Latin America
  • 6 References

Karst weathering processes

The chemical processes of karst formation basically include the following reactions:

  • The dissolution of carbon dioxide (COtwo) in water:

COtwo  + HtwoO → HtwoCO3

  • The dissociation of carbonic acid (HtwoCO3) in water:

HtwoCO3 + HtwoO → HCO3- + H3OR+

  • The dissolution of calcium carbonate (CaCO3) by acid attack:

Thief3  + H3OR+ → Catwo+ + HCO3- + HtwoOR

  • With a resulting total reaction:

COtwo  + HtwoO + CaCO3 → 2HCO3- + ACtwo+

  • The action of slightly acidic carbonated waters, producing the dissociation of the dolomite and subsequent contribution of carbonates:

CaMg (CO3)two + 2HtwoO + COtwo → CaCO3 + MgCO3 + 2HtwoO + COtwo

Factors necessary for appearance of karst relief:

  • The existence of a limestone rock matrix.
  • The abundant presence of water.
  • CO concentrationtwo appreciable in water; this concentration increases with high pressures and low temperatures.
  • Biogenic sources of COtwo. Presence of microorganisms, which produce COtwo through the breathing process.
  • Enough time for the action of the water on the rock.

Mechanisms for dissolution of host rock:

  • The action of aqueous solutions of sulfuric acid (HtwoSW4).
  • Volcanism, where lava flows form tubular caves or tunnels.
  • Physical erosive action of sea water that produces marine or coastal caves, due to the impact of waves and undermining of cliffs.
  • Coastal caves formed by the chemical action of seawater, with constant solubilization of host rocks.

Geomorphology of karst reliefs

Karst relief can form within or outside of a host rock. In the first case it is called internal karst, endocarstic or hypogenic relief, and in the second case external karst, exocarstic or epigenic relief.

Figure 2. Karst relief in Covadonga, Asturias, Spain. Source: Mª Cristina Lima Bazán via https://www.flickr.com/photos/[email protected] / 27435235767

-Internal karst or endocarstic relief

The underground water currents that circulate within the beds of carbonate rocks, dig internal courses within the large rocks, through the dissolution processes that we have mentioned..

Depending on the characteristics of the scour, different forms of internal karst relief originate.

Dry caves

Dry caves are formed when internal water currents leave these channels that have dug through the rocks..

Galleries

The simplest way of being dug by water inside a cave is the gallery. The galleries can be widened to form "vaults" or they can be narrowed and form "corridors" and "tunnels". They can also form "branched tunnels" and rises of water called "siphons".

Stalactites, stalagmites and columns

During the period when the water has just left its course inside a rock, the remaining galleries are left with a high degree of humidity, exuding drops of water with dissolved calcium carbonate..

When the water evaporates, the carbonate precipitates into a solid state and formations appear that grow from the ground called "stalagmites", and other formations grow hanging from the ceiling of the cave, called "stalactites".

When a stalactite and a stalagmite coincide in the same space, joining, a "column" is formed within the caves..

Cannons

When the roof of the caves collapses and collapses, "canyons" are formed. Thus, very deep cuts and vertical walls appear where surface rivers can circulate..

-External karst, exocarstic or epigenic relief

The dissolution of limestone by water can pierce the rock at its surface and form voids or cavities of different sizes. These cavities can be a few millimeters in diameter, large cavities several meters in diameter or tubular channels called "lapiaces".

As a lapiaz develops sufficiently and generates a depression, other karst landforms appear called "sinkholes", "uvalas" and "poljes".

Dolinas

The sinkhole is a depression with a circular or elliptical base, whose size can reach several hundred meters.

Frequently, water accumulates in the sinkholes which, by dissolving the carbonates, digs a funnel-shaped sink.

Grapes

When several sinkholes grow and join in a great depression, a "grape" is formed.

Poljés

When a large depression with a flat bottom and dimensions in kilometers is formed, it is called "poljé".

A poljé is in theory an immense grape, and within the poljé there are the smallest karst forms: uvalas and sinkholes..

In the poljés a network of water channels is formed with a sink that empties into groundwater.

Figure 3. Cueva del Fantasma, Aprada-tepui, Venezuela. (Observe the people on the left side of the image for size reference). Source: MatWr [CC BY-SA 4.0 (https://creativecommons.org/licenses/by-sa/4.0)], from Wikimedia Commons

Karst formations as life zones

In karst formations there are intergranular spaces, pores, joints, fractures, fissures and ducts, whose surfaces can be colonized by microorganisms.

Photic zones in karst formations

In these surfaces of the karst reliefs, three photic zones are generated depending on the penetration and intensity of the light. These zones are:

  • Entrance area: this area is exposed to solar irradiation with a daily day-night lighting cycle.
  • Twilight Zone: intermediate photic zone.
  • Dark zone: area where light does not penetrate.

Fauna and adaptations in the photic zone

The different forms of life and their adaptation mechanisms are directly correlated with the conditions of these photic zones.

The entry and twilight zones have tolerable conditions for a variety of organisms, from insects to vertebrates..

The dark zone presents more stable conditions than the superficial zones. For example, it is not affected by the turbulence of the winds and maintains a practically constant temperature throughout the year, but these conditions are more extreme due to the absence of light and the impossibility of photosynthesis..

For these reasons, deep karst areas are considered nutrient poor (oligotrophic), as they lack photosynthetic primary producers..

Other limiting conditions in karst formations

In addition to the absence of light in endocarstic environments, in karst formations there are other limiting conditions for the development of life forms.

Some environments with hydrological connections to the surface can suffer floods; desert caves can experience long periods of drought and volcanic tubular systems can experience renewed volcanic activity.

In internal caverns or endogenic formations, a variety of life-threatening conditions can also occur, such as toxic concentrations of inorganic compounds; sulfur, heavy metals, extreme acidity or alkalinity, lethal gases or radioactivity.

Microorganisms of endocarstic areas

Among the microorganisms that inhabit endocarstic formations we can mention bacteria, archaea, fungi and there are also viruses. These groups of microorganisms do not present the diversity that they show in surface habitats.

Many geological processes such as iron and sulfur oxidation, ammonification, nitrification, denitrification, anaerobic sulfur oxidation, reduction of sulfate (SO4two-), methane cyclization (formation of cyclic hydrocarbon compounds from methane CH4), among others, are mediated by microorganisms.

As examples of these microorganisms we can cite:

  • Leptothrix sp., which effects iron precipitation in the Borra caves (India).
  • Bacillus pumilis isolated from Sahastradhara caves (India), mediating calcium carbonate precipitation and calcite crystal formation.
  • Sulfur oxidizing filamentous bacteria Thiothrix sp., found in Lower Kane cave, Wyomming (USA).

Microorganisms of exocarstic areas

Some exokarst formations contain deltaproteobacteria spp., acidobacteria spp., Nitrospira spp. Y proteobacteria spp.

In the hypogenic or endokarstic formations species of the genera can be found: Epsilonproteobacteriae, Ganmaproteobacteriae, Betaproteobacteriae, Actinobacteriae, Acidimicrobium, Thermoplasmae, Bacillus, Clostridium Y Firmicutes, among others.

Landscapes of karst formations in Spain

  • Las Loras Park, designated a World Geopark by UNESCO, located in the northern part of Castilla y León.
  • Papellona Cave, Barcelona.
  • Ardales Cave, Malaga.
  • Santimamiñe Cave, Empty Country.
  • Covalanas Cave, Cantabria.
  • Caves of La Haza, Cantabria.
  • Miera Valley, Cantabria.
  • Sierra de Grazalema, Cádiz.
  • Tito Bustillo Cave, Ribadesella, Asturias.
  • Torcal de Antequera, Malaga.
  • Cerro del Hierro, Seville.
  • Macizo de Cabra, Subbética Cordobesa.
  • Sierra de Cazorla Natural Park, Jaén.
  • Anaga Mountains, Tenerife.
  • Massif of Larra, Navarra.
  • Rudrón Valley, Burgos.
  • Ordesa National Park, Huesca.
  • Sierra de Tramontana, Mallorca.
  • Stone Monastery, Zaragoza.
  • Enchanted City, Cuenca.

Landscapes of karst formations in Latin America

  • Lakes of Montebello, Chiapas, Mexico.
  • El Zacatón, Mexico.
  • Dolinas of Chiapas, Mexico.
  • Cenotes of Quintana Roo, Mexico.
  • Cacahuamilpa Caves, Mexico.
  • Tempisque, Costa Rica.
  • Roraima Sur Cave, Venezuela.
  • Charles Brewer Cave, Chimantá, Venezuela.
  • La Danta System, Colombia.
  • Gruta da Caridade, Brazil.
  • Cueva de los Tayos, Ecuador.
  • Cura Knife System, Argentina.
  • Mother of God Island, Chile.
  • Formation of El Loa, Chile.
  • Coastal area of ​​the Cordillera de Tarapacá, Chile.
  • Cutervo Formation, Peru.
  • Pucará Formation, Peru.
  • Umajalanta Cave, Bolivia.
  • Polanco Formation, Uruguay.
  • Vallemí, Paraguay.

References

  1. Barton, H.A. and Northup, D.E. (2007). Geomicrobiology in cave environments: past, current and future perspectives. Journal of Cave and Karst Studies. 67: 27-38.
  2. Culver, D.C. and Pipan, T. (2009). The biology of caves and other subterranean habitats. Oxford, UK: Oxford University Press.
  3. Engel, A.S. (2007). On the biodiversity of sulfidic karst habitats. Journal of Cave and Karst Studies. 69: 187-206.
  4. Krajic, K. (2004). Cave biologists unearth buried treasure. Science. 293: 2,378-2,381.
  5. Li, D., Liu, J., Chen, H., Zheng, L. and Wang, k. (2018). Soil microbial community responses to forage grass cultivation in degraded karst soils. Land Degradation and Development. 29: 4.262-4.270.
  6. doi: 10.1002 / ldr.3188
  7. Northup, D.E. and Lavoie, K. (2001). Geomicrobiology of caves: A review. Geomicrobiology Journal. 18: 199-222.

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